Никельфосфидный катализатор на основе мезопористого наносферического полимера в процессе гидрирования гваякола и фурфурола

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Получен нанесенный никельфосфидный катализатор in situ в условиях синтеза мезопористого резорцинформальдегидного полимера. Катализатор испытан в гидрировании гваякола и фурфурола в толуоле при давлении водорода 4 МПа. Исследованы характеристики гидрирования фурфурола в зависимости от давления водорода, массы загруженного катализатора, температуры и продолжительности процесса. Оценена активность полученного никельфосфидного катализатора в гидрировании смеси гваякола и фурфурола в толуоле.

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作者简介

Искандер Шакиров

Московский государственный университет имени М. В. Ломоносова

编辑信件的主要联系方式.
Email: sammy-power96@yandex.ru
ORCID iD: 0000-0003-2029-693X

химический факультет

俄罗斯联邦, Москва, 119991

Максим Бороноев

Московский государственный университет имени М. В. Ломоносова

Email: sammy-power96@yandex.ru
ORCID iD: 0000-0001-6129-598X

химический факультет; к. х. н.

俄罗斯联邦, Москва, 119991

Екатерина Ролдугина

Московский государственный университет имени М. В. Ломоносова

Email: sammy-power96@yandex.ru
ORCID iD: 0000-0002-9194-1097

химический факультет; к. х. н. 

俄罗斯联邦, Москва, 119991

Юлия Кардашева

Московский государственный университет имени М. В. Ломоносова

Email: sammy-power96@yandex.ru
ORCID iD: 0000-0002-6580-1082

химический факультет; к. х. н. 

俄罗斯联邦, Москва, 119991

Сергей Кардашев

Московский государственный университет имени М. В. Ломоносова

Email: sammy-power96@yandex.ru
ORCID iD: 0000-0003-1818-7697

химический факультет; к. х. н. 

俄罗斯联邦, Москва, 119991

参考

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2. Fig. 1. Micrograph (a) and size distribution of spherical particles (b) of mesoporous resorcinol-formaldehyde polymer.

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3. Fig. 2. Nitrogen adsorption–desorption isotherm of mesoporous resorcinol-formaldehyde polymer.

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4. Fig. 3. Diffraction pattern of a nickel phosphide catalyst deposited on a mesoporous polymer.

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5. Fig. 4. Micrograph of a nickel phosphide catalyst deposited on a mesoporous polymer (a) and the size distribution of Ni2P nanoparticles (b).

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6. Fig. 5. Spectra of temperature-programmed desorption of ammonia from a mesoporous polymer and a nickel phosphide catalyst.

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7. Fig. 6. Deconvolutions of Ni2p (a) and P2p (b) X-ray photoelectron spectra of nickel phosphide catalyst.

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8. Fig. 7. Conversion of furfural and selectivity of formation of its hydrogenation products in the presence of nickel phosphide catalyst depending on: (a) — temperature; (b) — hydrogen pressure; (c) — catalyst loading; (d) — duration of the hydrogenation process. *Reaction conditions: 50 μl furfural, 2 ml toluene, then for: (a) — 11 mg catalyst, 4 MPa H2, 4 h; (b) — 11 mg catalyst, 200°C, 4 h; (c) — 4 MPa H2, 200°C, 4 h; (d) — 4 MPa H2, 200°C, 11 mg catalyst.

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9. Fig. 8. Conversion of guaiacol and selectivity of formation of its hydrogenation products in the presence of nickel phosphide catalyst depending on: (a) — hydrogenation temperature; (b) — duration of the hydrogenation process. Reaction conditions: 100 μl guaiacol, 2 ml toluene, 25 mg catalyst, 4 MPa H2.

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