Mechanism of the Thermolysis of Magnesium Perylenetetracarboxylates

S. A. Naifert; Найферт С. А.; D. A. Zherebtsov; Жеребцов Д. А.; D. A. Uchaev; Учаев Д. А.; R. S. Morozov; Морозов Р. С.; K. R. Smolyakova; Смолякова К. Р.; E. M. Orlova; Орлова Е. М.; A. A. Pan’kova; Панькова А. А.; A. L. Sharova; Шарова А. Л.

doi:10.31857/S0044453723060201

Mechanism of the Thermolysis of Magnesium Perylenetetracarboxylates

Авторлар: Naifert S.A.¹, Zherebtsov D.A.¹, Uchaev D.A.¹, Morozov R.S.¹, Smolyakova K.R.¹, Orlova E.M.¹, Pan’kova A.A.¹, Sharova A.L.¹
Мекемелер:
1. South Ural State University
Шығарылым: Том 97, № 6 (2023)
Беттер: 850-859
Бөлім: ФИЗИЧЕСКАЯ ХИМИЯ НАНОКЛАСТЕРОВ, СУПРАМОЛЕКУЛЯРНЫХ СТРУКТУР И НАНОМАТЕРИАЛОВ
##submission.dateSubmitted##: 27.02.2025
##submission.datePublished##: 01.06.2023
URL: https://innoscience.ru/0044-4537/article/view/668723
DOI: https://doi.org/10.31857/S0044453723060201
EDN: https://elibrary.ru/KCONVW
ID: 668723

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Аннотация

Black-red and orange magnesium perylene-3,4,9,10-tetracarboxylate species are synthesized in the ion-exchange reaction at room temperature and by boiling an aqueous solution, respectively. Upon heating the two species to 500°C in argon, they reversibly lose 19–27 wt % of their crystallization water, and the products become black. X-ray diffraction analysis results show the preservation of the layered structure upon heating, which is confirmed via transmission electron microscopy. Exposure to a humid atmosphere rehydrates and restores the original structure. Thermolysis to 1000°С in argon produces a composite of MgO nanoparticles in a porous glassy carbon matrix. The stability of perylenetetracarboxylates up to 500°C makes them a promising candidate for synthesizing metal–organic frameworks.

Негізгі сөздер

carbon, perylenetetracarboxylates, metal–organic frameworks, thermal analysis

Әдебиет тізімі

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