Heterogeneous-catalytic reaction of hydrogenation-dehydrogenation of aromatic compounds as the basis of accumulation, storage, and production of chemically pure hydrogen

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The quality of hydrogen released from naphthenic substrates (bicyclohexyl, ortho-, meta-, and para-isomers of perhydroterphenyl) as a result of catalytic dehydrogenation over 3% Pt/C (sibunit) is studied as a key criterion for the high degree of regeneration and recyclization of hydrogen storage systems. It is shown that chemically pure hydrogen without impurities of methane and carbon oxides can be obtained by the dehydrogenation of liquid organic hydrogen carriers (LOHC) if the initial aromatic hydrocarbons and the naphthenic substrates obtained from them were previously thoroughly thermally treated before the hydrogenation and dehydrogenation reactions, respectively, in an inert gas.

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作者简介

А. Каlenchuk

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: akalenchuk@yandex.ru
俄罗斯联邦, 119992, Moscow; 119991, Moscow

V. Bogdan

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
俄罗斯联邦, 119992, Moscow; 119991, Moscow

L. Kustov

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
俄罗斯联邦, 119992, Moscow; 119991, Moscow

He Teng

Dalian Institute of Chemical Physics

Email: akalenchuk@yandex.ru
中国, Dalian

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2. Fig. 1. Chromatogram of gaseous products of the dehydrogenation reaction.

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