On the Thermodynamic Stability of Multicomponent Reactive Systems

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Derivation and analysis of conditions of the thermodynamic stability for multicomponent reactive systems are proposed based on transformations and different representations of the stability matrix. Stability boundaries and spinodal conditions in systems with chemical interaction of compounds are discussed.

作者简介

A. Toikka

St. Petersburg State University

Email: a.toikka@spbu.ru
198504, St. Petersburg, Russia

G. Misikov

St. Petersburg State University

Email: a.toikka@spbu.ru
198504, St. Petersburg, Russia

M. Toikka

St. Petersburg State University

编辑信件的主要联系方式.
Email: a.toikka@spbu.ru
198504, St. Petersburg, Russia

参考

  1. Gitterman M., Steinberg V. // J. Chem. Phys. 1976. V. 65. P. 847. https://doi.org/10.1063/1.433076
  2. Gitterman M., Steinberg V. // Ibid. 1978. V. 69. P. 2763. https://doi.org/10.1063/1.436873
  3. Glansdorff P., Prigogine I. Thermodynamic theory of Structure, Stability and Fluctuations. London: Wiley, 1971. 306 p.
  4. Gitterman M. J. Statist. Phys. 1990. V. 58. P. 707. https://doi.org/10.1007/BF01112772
  5. Ung S., Doherty M. Chem. Eng. Sci. 1995. V. 50. P. 3201. https://doi.org/10.1016/0009-2509(95)00159-3
  6. Fishtik I. J. Phys. Chem. B. 2005. V. 109. P. 3851. https://doi.org/10.1021/jp045863j
  7. Toikka A.M. Stability of Chemical and Phase Equilibrium: Alternative forms of Equations for Thermodynamic Analysis. In Mathematical Chemistry; Hong W.I., Ed.; Nova Science Publishers, Inc.: Singapore. 2010. P. 509.
  8. Жаров В.Т. // Журн. физ. химии. 1970. Т. 44. № 9. С. 1967.
  9. Gibbs J.W. The Collected Works. V. 1. Thermodynamics. London: Longmans and Green. 1931. 461 p.
  10. Сторонкин А.В. Термодинамика гетерогенных систем. Ч. 1–2. Л.: ЛГУ, 1967. 447 с.
  11. Arnold V.I. Contact geometry: The geometrical method of Gibbs’s thermodynamics. Proceedings of the Gibbs Symposium, Yale University, 1989 / G.D. Mostow, D.G. Caldi, Eds. Providence, RI, USA: American Mathematical Society – American Institute of Physics, 1990. P. 163.
  12. Gibbs J.W. // Trans. Connect. Acad. 1875. V. 3. P. 108.
  13. Тойкка А.М. // Журн. физ. химии. 1990. Т. 64. С. 2557.
  14. Gromov D., Toikka A. // J. Math. Chem. 2020. V. 58. P. 1219. https://doi.org/10.1007/s10910-020-01126-1
  15. Gromov D., Toikka A. // Entropy. 2020. V. 22. P. 1113. https://doi.org/10.3390/e22101113
  16. Gromov D., Toikka A. // Ibid. 2021. V. 23. P. 1548. https://doi.org/10.3390/e23111548
  17. Жаров В.Т., Первухин О.К. // Журн. физ. химии. 1972. Т. 46. № 8. С. 1970.
  18. Toikka A.M., Jenkins J.D. Chem. Eng. J. 2002. V. 89. № 1–3. P. 1. https://doi.org/10.1016/S1385-8947(01)00310-2
  19. Münster A. // Chemical Thermodynamics. Hoboken, NJ, USA: JohnWiley & Sons, 1970. 387 p.
  20. Prigogine I., Defay R. Chemical Thermodynamics. Harlow, UK: Longmans, Green and Co., 1954. 533 p.
  21. Tisza L. Generalized Thermodynamics. Cambridge, MA, USA: MIT Press, 1966. 384 p.
  22. Жаров В.Т. Вопросы термодинамики гетерогенных систем и теории поверхностных явлений. Вып. 2 / Под ред. А.В. Сторонкина. Л.: Изд-во Ленингр. ун-та, 1973. С. 35–52.

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