Temperature Dependence of Direct Current Conductivity in TiO2/Epoxy Polymer Dielectric Nanocomposites

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Abstract

A study is performed of the effect TiO2 nanoparticles have on the temperature dependence of the direct current conductivity of epoxy polymers. The value of direct current conductivity is determined by analyzing the frequency dependence of the complex permittivity in the 102–105 Hz range of frequencies. Two characteristic regions are found on the temperature dependence of direct current conductivity: the Vogel–Fulcher–Tammann dependence above the glass transition temperature (Tg), and the Arrhenius dependence below Tg, due apparently to a change in the mechanism of conduction after the freezing of ionic mobility at temperatures

About the authors

E. V. Rabenok

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: jane.rabenok@gmail.com
Chernogolovka, Moscow oblast, Russia

G. F. Novikov

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: jane.rabenok@gmail.com
Chernogolovka, Moscow oblast, Russia

L. M. Bogdanova

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: jane.rabenok@gmail.com
Chernogolovka, Moscow oblast, Russia

Yu. S. Bukichev

Institute of Problems of Chemical Physics, Russian Academy of Sciences; Moscow Aviation Institute (National Research University)

Email: jane.rabenok@gmail.com
Chernogolovka, Moscow oblast, Russia; 125993, Moscow, Russia

G. I. Dzhardimalieva

Institute of Problems of Chemical Physics, Russian Academy of Sciences; Moscow Aviation Institute (National Research University)

Author for correspondence.
Email: jane.rabenok@gmail.com
Chernogolovka, Moscow oblast, Russia; 125993, Moscow, Russia

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Copyright (c) 2023 Е.В. Рабенок, Г.Ф. Новиков, Л.М. Богданова, Ю.С. Букичев, Г.И. Джардималиева