Studying the electrochemical behavior of a smooth gold electrode in a solution of bridged 1,2,4-trioxalane in acetonitrile

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Abstract

The behavior of a smooth gold electrode in the medium of bridged 1,2,4-trioxalane in acetonitrile is studied by cyclic voltammetry and gravimetry methods. It is found that during the cathodic process, the reduction of the peroxide bond in the bridged 1,2,4-trioxalane molecule takes place at the electrode surface followed by the formation of a diketone moiety. During anodic oxidation, the formation of colloidal gold particles is detected.

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About the authors

M. V. Polyakov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Author for correspondence.
Email: SatPolyak@yandex.ru
Russian Federation, Moscow, 119991

M. D. Vedenyapina

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Russian Federation, Moscow, 119991

A. M. Skundin

A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Russian Federation, Moscow, 119071

I. A. Yaryomenko

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Russian Federation, Moscow, 119991

P. S. Radulov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: SatPolyak@yandex.ru
Russian Federation, Moscow, 119991

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Supplementary files

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1. JATS XML
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2. Scheme 1. Obtaining the substrate under study 3.

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3. Fig. 1. CBA 3 in the cathodic region at the Au electrode, ν = 100, 150, 200, 250, 250, 300, 350, 350, 400, 450, 500 mV/s.

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4. Fig. 2. Dependences of Ipc - ν0.5 for the first (a) and second (b) cathode peaks of CBA.

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5. Fig. 3. CBA 3 in the anodic region at the Au electrode, ν = 100, 150, 200, 250, 250, 300, 350, 350, 400, 450, 500 mV/s.

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6. Fig. 4. Dependence of Ip,a on ν0.5.

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7. Fig. 5. Mass change of the gold anode, at I = 5 mA, in MeCN solution, the concentration of compound 3 was 0.05 M.

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8. Scheme 2. Electrochemical corrosion of gold in the presence of compound 3 in acetonitrile medium.

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9. Scheme 3. Cathodic reduction reaction of compound 3.

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