Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

V. M. Zelikman; Зеликман В. М.; K. I. Maslakov; Маслаков К. И.; I. A. Ivanin; Иванин И. А.; I. G. Tarkhanova; Тарханова И. Г.

doi:10.31857/S0044453723090273

Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

作者: Zelikman V.M.¹, Maslakov K.I.¹, Ivanin I.A.¹, Tarkhanova I.G.¹
隶属关系:
1. Faculty of Chemistry, Moscow State University
期: 卷 97, 编号 9 (2023)
页面: 1239-1247
栏目: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
##submission.dateSubmitted##: 26.02.2025
##submission.datePublished##: 01.09.2023
URL: https://innoscience.ru/0044-4537/article/view/668656
DOI: https://doi.org/10.31857/S0044453723090273
EDN: https://elibrary.ru/XQBDHD
ID: 668656

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详细

A set of silica gel-immobilized compounds is synthesized that consists of ethylimidazole cations and anions of phosphotungstic acid (lacunar (PW11) or mixed (PW11M), where M = Zn, Ni, Cu, Co, Mn). The composition and textural characteristics of the compounds are determined by physicochemical means (IR spectroscopy, XPS, SEM/EDX, adsorption). The synthesized heterogeneous composites are active in the oxidation of sulfur- and nitrogen-containing components of petroleum feedstocks with hydrogen peroxide. A comparative analysis is performed of the samples’ catalytic properties in the oxidation of both individual substrates (thiophene, dibenzothiophene, methyl phenyl sulfide, pyridine) and their mixtures.

关键词

oxidative desulfurization, oxidative denitrogenation, polyoxometalates, immobilized catalysts

参考

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