Optical ceramics obtained by hot pressing of CVD-ZnSe powder

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The influence of mechanical grinding conditions of high-purity CVD zinc selenide (ZnSe) powders on their particle size distribution, their sintering process, and the transparency of optical ceramics has been studied. Powders with an optimal granulometric composition were obtained, having an average particle size of 0.3 μm with a maximum of not more than 1 μm. These parameters were achieved by grinding the powders in a planetary ball mill for 20 hours at a grinding bowl rotation speed of 150 rpm. ZnSe optical ceramics are fabricated by a combination of hot pressing and subsequent hot isostatic pressing of CVD powders. The maximum transmission for 2 mm thick samples was 69% (close to theoretically achievable) at a wavelength of 14 μm. The combination of characteristics of CVD ZnSe powders subjected to additional grinding shows their promise for use in optical ceramic technology.

Full Text

Restricted Access

About the authors

S. S. Balabanov

G.G. Devyatykh Institute of Chemistry of High-Purity Substances of RAS

Author for correspondence.
Email: timofeeva@ihps-nnov.ru
Russian Federation, Nizhny Novgorod, 603137

N. A. Timofeeva

G.G. Devyatykh Institute of Chemistry of High-Purity Substances of RAS

Email: timofeeva@ihps-nnov.ru
Russian Federation, Nizhny Novgorod, 603137

T. O. Evstropov

G.G. Devyatykh Institute of Chemistry of High-Purity Substances of RAS

Email: timofeeva@ihps-nnov.ru
Russian Federation, Nizhny Novgorod, 603137

D. Yu. Kosyanov

Far Eastern Federal University

Email: timofeeva@ihps-nnov.ru
Russian Federation, Vladivostok, 690922

A. V. Naumova

G.G. Devyatykh Institute of Chemistry of High-Purity Substances of RAS

Email: timofeeva@ihps-nnov.ru
Russian Federation, Nizhny Novgorod, 603137

S. V. Filofeev

G.G. Devyatykh Institute of Chemistry of High-Purity Substances of RAS

Email: timofeeva@ihps-nnov.ru
Russian Federation, Nizhny Novgorod, 603137

References

  1. Page R.H., DeLoach L.D., Wilke G.D. et al. // Cr2+-doped II-VI crystals: new widely-tunable, room-temperature mid-IR lasers, in: LEOS ’95. IEEE Lasers Electro-Optics Soc. 1995 Annu. Meet. 8th Annu. Meet. Conf. Proc.30–31 October. San Francisco, 1995. P. 449. https://doi.org/10.1109/LEOS.1995.484795
  2. Adams J.J., Bibeau C., Page R.H. et al. // Opt. Lett. 1999. V. 24. № 23. P. 1720. https://doi.org/10.1364/OL.24.001720
  3. Schepler K.L., Peterson R.D., Berry P.A. et al. // IEEE J. Sel. Top. Quantum Electron. 2005. V. 11. № 3. P. 713. https://doi.org/10.1109/JSTQE.2005.850570
  4. Firsov K.N., Gavrishchuk E.M., Ikonnikov V.B. et al. // Laser Phys. Lett. 2016. V. 13. № 5. P. 055002. https://doi.org/10.1088/1612-2011/13/5/055002
  5. Kurashkin S.V., Martynova O.V., Savin D.V. et al. // Laser Phys. Lett. 2019. V. 16. № 7. P. 075801. https://doi.org/10.1088/1612-202X/ab21cd
  6. Balabanov S.S., Firsov K.N., Gavrishchuk E.M. et al. // Laser Phys. Lett. 2019. V. 16. № 5. P. 055004. https://doi.org/10.1088/1612-202X/ab09e8
  7. Palashov O.V., Starobor A.V., Perevezentsev E.A. et al. // Materials (Basel). 2021. V. 14. № 14. P. 3944. https://doi.org/10.3390/ma14143944
  8. Dormidonov A.E., Firsov K.N., Gavrishchuk E.M. et al. // Phys. Wave Phenom. 2020. V. 28. № 3. P. 222. https://doi.org/10.3103/S1541308X20030073
  9. Timofeeva N., Balabanov S., Li J. // Ceramics. 2023. V. 6. № 3. P. 1517. https://doi.org/10.3390/ceramics6030094
  10. Yavetskiy R.P., Balabanov A.E., Parkhomenko S.V. et al. // J. Adv. Ceram. 2021. V. 10. № 1. P. 49. https://doi.org/10.1007/s40145-020-0416-3
  11. Karki K., Yu S., Fedorov V. et al. // Opt. Mater. Express. 2020. V. 10. № 12. P. 3417. https://doi.org/10.1364/OME.410941
  12. Yu S., Carloni D., Wu Y. // J.Am. Ceram. Soc. 2020. V. 103. № 8. P. 4159. https://doi.org/10.1111/jace.17144
  13. Zhou G., Calvez L., Delaizir G. et al. // Optoelectron. Adv. Mater. Rapid Commun. 2014. V. 8. P. 436.
  14. Yu S., Wu Y. // J.Am. Ceram. Soc. 2019. V. 102. № 12. P. 7089. https://doi.org/10.1111/jace.16612
  15. Luo Y., Yin M., Chen L. et al. // Opt. Mater. Express. 2021. V. 11. № 8. P. 2744. https://doi.org/10.1364/OME.432380
  16. Wei S., Zhang L., Yang H. et al. // Opt. Mater. Express. 2017. V. 7. № 4. P. 1131. https://doi.org/10.1364/OME.7.001131
  17. Luo Y., Yin M., Chen L. et al. // Ceram. Int. 2022. V. 48. № 3. P. 3473. https://doi.org/10.1016/j.ceramint.2021.10.125
  18. Gao J.L., Liu P., Zhang J. et al. // Solid State Phenom. 2018. V. 281. P. 661. https://doi.org/10.4028/www.scientific.net/SSP. 281.661
  19. Гаврищук Е.М. // Неорган. материалы. 2003. Т. 39. № 9. С. 1030. https://doi.org/10.1023/A:1025529017192
  20. Li J., Liu J., Liu B. et al. // J. Eur. Ceram. Soc. 2014. V. 34. № 10. P. 2497. https://doi.org/10.1016/j.jeurceramsoc.2014.03.004
  21. Parkhomenko S., Balabanov A., Kryzhanovska O. et al. // Ceram. Int. 2023. V. 49. № 17. P. 29048. https://doi.org/10.1016/j.ceramint.2023.06.179
  22. Гаврищук Е.М., Савин Д.В., Иконников и др. // Неорган. материалы. 2006. Т. 42. № 8. С. 928. https://doi.org/10.1134/S0020168506080061
  23. Пермин Д.А., Беляев А.В., Кошкин В.А. и др. // Неорган. материалы. 2021. Т. 57. № 8. С. 901. https://doi.org/10.31857/S0002337X21080248
  24. Морозова Н.К., Плотниченко В.Г., Гаврищук Е.М. и др. // Неорган. материалы. 2003. Т. 39. № 8. С. 920. https://doi.org/10.1023/A:1025004808839
  25. Балабанов С.С., Гаврищук Е.М., Гладилин А.А. и др. // Неорган. материалы. 2019. Т. 55. № 5. С. 459. https://doi.org/10.1134/S0002337X19050014
  26. Papynov E.K., Portnyagin A.S., Modin E.B. et al. // Mater. Charact. 2018. V. 145. P. 294. https://doi.org/10.1016/j.matchar.2018.08.044
  27. Goldstein A., Krell A. // J.Am. Ceram. Soc. 2016. V. 99. № 10. P. 3173. https://doi.org/10.1111/jace.14553
  28. Садовников С.И., Сергеева С.В. // Журн. неорган. химии. 2023. Т. 68. № 4. С. 444. https://doi.org/10.1134/S0036023623600120
  29. Симоненко Е.П., Симоненко Н.П., Гордеев А.Н. и др. // Журн. неорган. химии. 2018. Т. 63. № 11. С. 1465. https://doi.org/10.1134/S0044457X1811017X

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Effect of milling time (0, 6, 12, 20 and 40 h) on the integral curves of particle size distribution volume curves for CVD ZnSe powders.

Download (140KB)
Indexing metadata
3. Fig. 2. Effect of milling time on specific surface area SBET and equivalent particle diameter dBET of CVD ZnSe powders.

Download (88KB)
Indexing metadata
4. Fig. 3. Microphotographs of CVD powders of ZnSe after milling for 2 (a) and 60 h (b).

Download (808KB)
Indexing metadata
5. Fig. 4. Appearance of ZnSe ceramic samples from CVD powders with different milling times.

Download (1MB)
Indexing metadata
6. Fig. 5. Transmission spectra of ZnSe ceramics obtained from CVD powders with milling times of 0, 2, 6, 12, and 20 h.

Download (170KB)
Indexing metadata
7. Fig. 6. Photographs of pores in the volume of ZnSe 2 (a) and 20 (b) ceramics.

Download (189KB)
Indexing metadata
8. Fig. 7. Histograms of grain size distribution for ZnSe ceramics: samples 0 (a), 12 (b), 20 (c).

Download (157KB)
Indexing metadata
9. Fig. 8. Photographs of microstructures of ZnSe ceramics: samples 6 (a) and 20 (b).

Download (793KB)
Indexing metadata

Copyright (c) 2024 Russian Academy of Sciences