Synthesis and structure of silver halide complexes [Ph3PCH=CH2]n[Ag2Br3]n, [Ph3PCH=CH2]n[Ag5Br6]n and [Ph3PCH2CH=CHCH2PPh3][Ag2I4]

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
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Рұқсат жабық Тек жазылушылар үшін

Аннотация

By the interaction of silver bromide with (2-bromoethyl)- and vinyltriphenylphosphonium bromides, as well as silver iodide with but-2-ene-1,4-diyl-bis(triphenylphosphonium) diiodide in DMSO, haloargentate complexes [Ph3PCH=CH2]n[Ag2Br3]n (I), [Ph3PCH=CH2]n[Ag5Br6]n (II) and [Ph3PCH2CH=CHCH2PPh3][Ag2I4] (III) were synthesized. The obtained products were characterized by IR spectroscopy and X-ray diffraction analysis (CCDC No. 2173339 (I), 2172944 (II), 1985085 (III)). According to X-ray diffraction data, compounds I–III consist of organyltriphenylphosphonium cations with tetrahedrally coordinated phosphorus atoms and the corresponding haloargentate anions of 1D-polymeric (I, II) or non-polymeric (III) structure. The anions I and II are “cross-linked” from tetrahedral {AgBr4} fragments, while anion III – from two trigonal fragments {AgBr3}. In all the resulting complexes, the Ag centers are additionally connected to each other by argentophilic contacts with Ag···Ag distances in the range of 2.8162(12)–3.371(2) Å.

Толық мәтін

Рұқсат жабық

Авторлар туралы

D. Shevchenko

South Ural State University (National Research University)

Хат алмасуға жауапты Автор.
Email: Shepher56@gmail.com
Ресей, Chelyabinsk, 454080

A. Zhizhina

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Ресей, Chelyabinsk, 454080

A. Efremova

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Ресей, Chelyabinsk, 454080

V. Sharutin

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Ресей, Chelyabinsk, 454080

O. Sharutina

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Ресей, Chelyabinsk, 454080

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Жүктеу
2. Fig. 1. Structure of complex I (hydrogen atoms are not shown) (a); fragment of the polymer chain [Ag2Br3 (b).

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3. Fig. 2. Structure of complex II (hydrogen atoms are not shown) (a); view inside the tube [Ag5Br6 (µ5-Br ions are not shown) (b); fragment of a polymer tube-shaped chain [Ag5Br6 (c).

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4. Fig. 3. Structure of complex III (hydrogen atoms are not shown).

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5. Fig. 4. Crystal organization of complex I.

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6. Fig. 5. Crystal organization of complex II.

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7. Fig. 6. Crystal organization of complex III.

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