Synthesis and structure of silver halide complexes [Ph3PCH=CH2]n[Ag2Br3]n, [Ph3PCH=CH2]n[Ag5Br6]n and [Ph3PCH2CH=CHCH2PPh3][Ag2I4]

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Abstract

By the interaction of silver bromide with (2-bromoethyl)- and vinyltriphenylphosphonium bromides, as well as silver iodide with but-2-ene-1,4-diyl-bis(triphenylphosphonium) diiodide in DMSO, haloargentate complexes [Ph3PCH=CH2]n[Ag2Br3]n (I), [Ph3PCH=CH2]n[Ag5Br6]n (II) and [Ph3PCH2CH=CHCH2PPh3][Ag2I4] (III) were synthesized. The obtained products were characterized by IR spectroscopy and X-ray diffraction analysis (CCDC No. 2173339 (I), 2172944 (II), 1985085 (III)). According to X-ray diffraction data, compounds I–III consist of organyltriphenylphosphonium cations with tetrahedrally coordinated phosphorus atoms and the corresponding haloargentate anions of 1D-polymeric (I, II) or non-polymeric (III) structure. The anions I and II are “cross-linked” from tetrahedral {AgBr4} fragments, while anion III – from two trigonal fragments {AgBr3}. In all the resulting complexes, the Ag centers are additionally connected to each other by argentophilic contacts with Ag···Ag distances in the range of 2.8162(12)–3.371(2) Å.

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About the authors

D. P. Shevchenko

South Ural State University (National Research University)

Author for correspondence.
Email: Shepher56@gmail.com
Russian Federation, Chelyabinsk, 454080

A. I. Zhizhina

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Russian Federation, Chelyabinsk, 454080

A. N. Efremova

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Russian Federation, Chelyabinsk, 454080

V. V. Sharutin

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Russian Federation, Chelyabinsk, 454080

O. K. Sharutina

South Ural State University (National Research University)

Email: Shepher56@gmail.com
Russian Federation, Chelyabinsk, 454080

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Supplementary files

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2. Fig. 1. Structure of complex I (hydrogen atoms are not shown) (a); fragment of the polymer chain [Ag2Br3 (b).

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3. Fig. 2. Structure of complex II (hydrogen atoms are not shown) (a); view inside the tube [Ag5Br6 (µ5-Br ions are not shown) (b); fragment of a polymer tube-shaped chain [Ag5Br6 (c).

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4. Fig. 3. Structure of complex III (hydrogen atoms are not shown).

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5. Fig. 4. Crystal organization of complex I.

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6. Fig. 5. Crystal organization of complex II.

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7. Fig. 6. Crystal organization of complex III.

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