Chemical Generation And Reactivity Of Highly Oxidized Oxo-Species Of Water-Soluble µ-Carbide Dimer Ruthenium(IV)Phthalocyaninate

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The chemical generation of highly oxidized species of µ-carbido dimer water-soluble ruthenium sulfophthalocyaninate in reaction with tert-butyl hydroperoxide was studied using spectral methods. The regularities of the active species formation have been established and a reaction mechanism has been proposed. The coordinating ability of the dimeric complex is shown to determine the possibility of the π-radical cation and diradical cation species formation. The influence of peroxide concentration and pH of the medium on the type of the generated active species capable of oxidizing not only synthetic dye, but also organic peroxide, is demonstrated.

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S. Zaitseva

G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Science

编辑信件的主要联系方式.
Email: svz@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045

S. Zdanovich

G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Science

Email: svz@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045

V. Sukharev

Ivanovo State University of Chemistry and Technology

Email: svz@isc-ras.ru
俄罗斯联邦, Ivanovo, 153000

O. Koifman

G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Science; N.D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences

Email: svz@isc-ras.ru
俄罗斯联邦, Ivanovo, 153045; Moscow, 119991

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2. Scheme 1

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3. Scheme 2

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4. Fig. 1. Change in the ESP of the μ-carbidodimeric ruthenium(IV) sulfophthalocyaninate (C1 = 5.6 × 10-6 mol/l) during reaction with tBuOOH in water at 295 K: a) CtBuOOH = 3.68 × 10-3 mol/l; a') EPR spectrum of compound 2 at 120K; a") distribution spin density of form 2; b) StBuOOH = 6.4 × 10-2 mol/l; c) StBuOOH = 1.2 × 10-1 mol/l; spectral curves: 1 – the initial dimer 1; 2 – π-cation radical (one–electron oxidized form 2); 3 - dication-diradical (two-electron oxidized form 3); 4 – reduced form 2'.

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5. Fig. 2. IR spectra of aqueous solution 1 (C1 = 5.6 × 10-6 mol/l) (a), mixtures 1/tBuOOH (StBuOOH = 5.8 × 10-3 mol/l) (b), mixtures 1/tBuOOH (StBuOOH = 6.4 × 10-2 mol/l) (c), buffer solution of a mixture of 1/tBuOOH at pH 9 (CtBuOOH = = 9.83 × 10-3 mol/l) (g).

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6. Fig. 3. Mass spectrum of the reaction mixture 1/tBuOOH (CtBuOOH = (0.9–6) × 10-2 mol/l): a) an aqueous solution; b) a buffer solution at pH 9.

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7. Fig. 4. Change of ESP complex 1 (C1 = 5.6 × 10-6 mol/l) during reaction with tert-butylhydroperoxide (CtBuOOH = 9.83 × 10-3 mol/l) in buffer solution (pH 9) at 295 K: formation of alkyl peroxo complex (a), dependence of ln (C0/C0) on τ in the band at λ = 605 nm (a'); formation of a dication-diradical from an alkyl peroxo complex (b); spectral curves: 1 – the initial dimer, 2 – alkylperoxocomplex 4, 3 – dication-diradical 3.

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8. Fig. 5. Dependence of lgkef–lgCtBuOOH for reaction 1 (C1 = 5.6 × 10-6 mol/L) with tBuOOH: 1 – one-electron oxidation of the complex (StBuOOH = 3.68 × 10-3 ÷ ÷ 1.2 × 10-2 mol/L); 2 – two-electron oxidation of the complex (StBuOOH = 3.85 × 10-2 ÷ 8.8 × 10-2 mol/l).

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9. Fig. 6. Changes in the ESP of the dye during its oxidative conversion in the presence of active forms of complex 1 (C1 = 5.6 × 10-6 mol/l, CtBuOOH = 3.68 × × 10-3-6.2 × 10-2 mol/L) at 298 K: a – OrangeII (COrangeII = 8.64 × 10–4 mol/l)/form 4 in buffer solution (pH 9): 1 – immediately after adding the dye, 2 – after 5 minutes; b – OrangeII/ form 3: 1 – immediately after adding the dye, 2 – after 18 minutes; c – RB/ form 3 (CRB = 1.7 × 10-5 mol / l): 1 – immediately after adding the dye, 2 – after 36 minutes.

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10. Fig. 7. Dependence of ln(C0/Cτ) on time (τ) for the oxidation reaction of OrangeII in the band at λ = 485 nm: 1 – with form 4, 2 – with form 3, 3 – with form 2.

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11. Figure 8. Conversion of the dye (%) with its periodic addition to the active form of complex 1: a – OrangeII (COrangeII = 8.64 × 10-4 mol/l) in the presence of form 4; b – RB (CRB = 1.7 × 10-5 mol/l) in the presence of form 3; c – change in the value of kef when conducting six OrangeII conversion cycles involving forms 2-4.

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