Chemical reactions rates in the TEFIS database on thermophysical properties of dense plasma

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Since the 1960s at the Keldysh Institute of Applied Mathematics team led by N.N. Kalitkin creates the TEFIS database on the thermophysical properties of substances. In recent years, this database has included a section on the rates of chemical reactions that describe several relevant processes. For this, new mathematical methods for regression of experimental data measured with significant errors were developed. This paper presents the current state of work in this area.

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作者简介

O. Topor

Lomonosov Moscow State University

编辑信件的主要联系方式.
Email: topor.oi15@physics.msu.ru
俄罗斯联邦, Moscow

A. Belov

Lomonosov Moscow State University; Peoples’ Friendship University of Russia

Email: topor.oi15@physics.msu.ru
俄罗斯联邦, Moscow; Moscow

L. Borodachev

Lomonosov Moscow State University

Email: topor.oi15@physics.msu.ru
俄罗斯联邦, Moscow

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2. Fig. 1. Reaction N2O + M → N2 + O + M. Dots are experiments. The solid line is the TEFIS approximation, the dotted line is the boundaries of its confidence interval

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3. Fig. 2. Reaction N2O + M → N2 + O + M. Relation of the TEFIS approximation to approximations from the NIST database. Numbers near the lines are the reference number from the reference list

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4. Fig. 3. Concentrations of the most important components during combustion of H2 + O2

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5. Fig. 4. Deviations of concentrations from reference concentrations during reduction of the reaction system

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