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Volume 125, Nº 4 (2024)

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ЭЛЕКТРИЧЕСКИЕ И МАГНИТНЫЕ СВОЙСТВА

New Magnetic Materials and Technologies: Experiment and Theory

Gavrilyuk A., Semirov A., Marchenkov V.

Resumo

This article presents a brief review of works devoted to the latest research by a number of Russian groups involved in the development, creation, and study of the physical properties of new magnetic materials and the phenomena observed in them. These studies are of both great fundamental and practical interest for various fields of science, engineering, and new technologies.

Fizika metallov i metallovedenie. 2024;125(4):377-382
pages 377-382 views

Peculiarities of the Spin Wave Spectrum in Transversely Confined YIG Microwaveguides with Inhomogeneous Magnetization Profile

Aleksandrova Y., Beginin E., Sheshukova S., Sadovnikov A.

Resumo

A study of spin wave spectra in a two-layer structure of iron-yttrium garnet (YIG) with different magnitudes of the saturation magnetizations of the layers has been carried out. Different modes of spin wave propagation (reciprocal, nonreciprocal, single-wave) depending on the type of structure and width of the central waveguide are investigated. The classification of spin wave spectra is carried out, and the class of guided, outgoing, and edge spin modes is identified. In particular, it is shown that in a system of planar magnetic comb-type LS-type (Ms1 < Ms2) microwave guide tubes with periodic boundary conditions, two non-contiguous frequency regions of existence of guided modes of the central waveguide are observed for a width w of the central waveguide. Two adjacent frequency regions exist in the system of planar magnetic comb-type HS-type (Ms1 > Ms2) microwave guide tubes at any values of the width of the central waveguide: in the high-frequency region, the mode with outflowing modes of the structure is realized, while in the low-frequency region, the mode with guided modes of the central waveguide is realized. It is shown that in systems of both types in the region of strongly inhomogeneous magnetic fields there can exist modes of boundary waves having a mutual character of propagation. The results obtained can be used to expand and clarify the physics of wave processes in complicated magnetic structures.

Fizika metallov i metallovedenie. 2024;125(4):383-393
pages 383-393 views

Magnetic Properties of a Nickel–Zinc Ferrite Powder with Different Degrees of Dispersion

Bobuyok S., Surzhikov A., Lysenko E., Nikolaev E., Salnikov V.

Resumo

The influence of the degree of dispersion of a nickel–zinc ferrite powder of a Ni0.7Zn0.3Fe2O4 composition on its magnetic properties has been considered. The material has been synthesized using the ceramic technology with preliminary mechanical activation of precursors. The degree of dispersion has been varied using different modes of its dry grinding in a ball mill. The patterns of the changes in saturation magnetization and the coercive force as a function of grinding modes and a specific surface area of the ferrite powder have been established. The changes in the pattern of the magnetic phase transition in the region of the Curie temperature of materials with different degrees of dispersion have been determined.

Fizika metallov i metallovedenie. 2024;125(4):394-402
pages 394-402 views

Nanostructured Coatings of 3d-Metals Produced by Green Chemistry Methods: Analysis of Inhomogeneities by Static and Dynamic Magnetic Methods

Vazhenina I., Stolyar S., Komogortsev S., Li O., Iskhakov R., Velikanov D., Cheremiskina E., Nemtsev I.

Resumo

The study investigates carbon-containing coatings of 3d-metals (Ni, Co, Fe) produced by chemical deposition method using arabinogalactan. The coatings were analyzed using X-ray diffraction, FMR, and M(H) magnetometry. Measurement of M(H) in plane and perpendicular to the plane of the magnetic coatings allowed determining the distribution of demagnetizing factor in the studied coatings. The obtained distributions of the demagnetizing factor were used to analyze the angular dependences of the ferromagnetic resonance field. The values of magnetization and perpendicular anisotropy field were estimated. The paper illustrates the effect of texture on the magnetic parameters.

Fizika metallov i metallovedenie. 2024;125(4):403-412
pages 403-412 views

Morphology and Magnetic Properties of Ni Nanowires in Thin Film Anodic Alumina Templates

Dryagina A., Gorkovenko A., Kulesh N., Kurdyukov E., Viblaya A., Yushkov A., Veryasova A., Pastukhov V., Kalashnikova A., Vaskovsky V.

Resumo

The features of the morphology and magnetic properties of Ni nanowire arrays have been studied. Aluminum oxide matrices are used as a template for electrolytic deposition of nanowires. The matrices are obtained by anodizing the aluminum films with a thickness of 2 μm that are formed on glass substrates by high frequency ion sputtering. Electrochemical deposition of the metal is carried out using direct and alternating currents. Morphology and microstructure studies show that the nanowire arrays are polycrystalline and have a branched dendritic structure due to the morphological features of aluminum oxide matrices. A relationship between the magnetization reversal patterns and the modes of electrodeposition of Ni nanowire arrays is established. The process of magnetization reversal of an array of this kind of structures is simulated.

Fizika metallov i metallovedenie. 2024;125(4):413-419
pages 413-419 views

Superparamagnetic Relaxation in Ensembles of Ultrasmall Ferrihydrite Nanoparticles

Knyazev Y., Balaev D., Skorobogatov S., Velikanov D., Bayukov O., Stolyar S., Ladygina V., Krasikov A., Iskhakov R.

Resumo

The paper examines the impact of interparticle interactions on the superparamagnetic relaxation of ultrasmall nanoparticle ensembles, using Fe2O3∙nH2O iron oxyhydroxide (ferrihydrite) nanoparticles as an example. Two samples were analyzed: ferrihydrite of biogenic origin (with an average particle size of d ≈ 2.7 nm) with a natural organic shell, and a sample (with d ≈ 3.5 nm) that underwent low-temperature annealing, during which the organic shell was partially removed. The DC and AC magnetic susceptibilities (χ′(T), χ′′(T)) in a small magnetic field in the superparamagnetic (SPM) blocking region of the nanoparticles were measured. The results show that an increase in interparticle interactions leads to an increase in the SPM blocking temperature from 28 to 52 K according to DC magnetization data. It is shown that below the SPM blocking temperature, magnetic interactions of nanoparticles lead to the formation of a collective state similar to spin glass in bulk materials. The scaling approach reveals that the dynamics of correlated magnetic moments on the particle surface slow down with increasing interparticle interactions. Simulation of χ′′(T) dependence has shown that the dissipation of magnetic energy occurs in two stages. The first stage is directly related to the blocking of the magnetic moment of nanoparticles, while the second stage reflects the spin-glass behavior of surface spins and strongly depends on the strength of interparticle interactions.

Fizika metallov i metallovedenie. 2024;125(4):420-429
pages 420-429 views

Structure and Magnetic Properties of Iron Oxide Nanoparticles Subjected to Mechanical Treatment

Kurlyandskaya G., Burban E., Neznakhin D., Yushkov A., Larrañaga A., Melnikov G., Svalov A.

Resumo

Iron oxide nanoparticles have been fabricated using the electric wire explosion (EWE) technique. The structure and magnetic properties of the nanoparticles have been analyzed before and after mechanical grinding in a ball mill for different time periods, focusing on potential bioapplications. The phase composition of the nanoparticles (70% Fe3O4, 30% Fe2O3) has remained unchanged despite the mechanical effects. The average nanoparticle size has not been affected either. The observation of the Verwey transition in the studied nanoparticles, along with the structural data, provides a better understanding of the physical properties of EWE ensembles of nanoparticles in different states. The analysis of the structure and magnetic properties reveals the development of a material with a high level of internal stress. This finding may be of interest for bioapplications due to its potential impact on the material performance.

Fizika metallov i metallovedenie. 2024;125(4):430-437
pages 430-437 views

Magnetocaloric and Magnetostrictive Properties of the Tb(Co,In)2 Laves Phases

Morozov D., Politova G., Ganin M., Politov M., Mikhailova A., Filimonov A.

Resumo

Multicomponent polycrystalline TbInxCo2–x (with х = 0–0.2) solid solutions are prepared for the first time, and their crystal structure and magnetic, magnetocaloric, and magnetostrictive properties are studied. X-ray diffraction patterns taken at room temperature demonstrate mainly the presence of the cubic C15 Laves phase in all samples. As the indium content increases to x = 0.1, the lattice parameter is found to increase; the further increase in the indium content to х = 0.2 leads to a decrease in the lattice parameter. In this case, the Curie temperature TC monotonically increases to 245 K. The isotheral magnetic entropy change ΔSmag is calculated in accordance with magnetic measurements using the thermodynamic Maxwell’s relation. At a magnetic field change from 0 to 1.8 T, the maximum entropy change monotonically decreases and, for composition with x = 0.2, is 1.8 J/(kg∙К). As the indium content increases to x = 0.05, the volume magnetostriction increases. The further increase in the indium concentration leads to the decrease in the peak values and their shift to high temperatures.

Fizika metallov i metallovedenie. 2024;125(4):438-446
pages 438-446 views

Effect of Bismuth Oxide on the Structure, Electrical Resistance and Magnetization of Lithium Zinc Ferrite

Nikolaevа S., Elkina Y., Lysenko E., Nikolaev E., Vlasov V.

Resumo

The structural, electrical, and magnetic properties of lithium zinc ferrite prepared by ceramic technology have been studied. The composition of lithium zinc ferrite is Li0.4Fe2.4Zn0.2O4 with 1 and 2 wt % bismuth oxide. The addition of Bi2O3 prior to sintering of the samples has been shown to affect the structural, electrical, and magnetic properties of the ferrite. A significant increase in density from 4.47 to 4.65 g/cm3 and a decrease in porosity from 4.8 to 2.3% have been observed when the concentration of bismuth oxide has been increased to 2 wt %. The Bi2O3-containing samples have higher specific electrical resistivity compared to that of the additive-free lithium zinc ferrite. The introduction of bismuth oxide has reduced the specific saturation magnetization from 70.55 to 54.76 G cm3/g. The Curie temperature has not changed significantly. An optimal combination of macroscopic properties of ferrite has been found at 1 wt % Bi2O3 concentration.

Fizika metallov i metallovedenie. 2024;125(4):447-452
pages 447-452 views

The Hall Effect in Single Crystals of Topological Semimetals WTe2 and MoTe2

Perevalova A., Naumov S., Fominykh B., Marchenkova E., Liang S., Marchenkov V.

Resumo

The Hall effect in single crystals of topological semimetals WTe2 and MoTe2 is studied in the temperature range from 2 to 100 K and in magnetic fields up to 9 T. It is established that the Hall resistivity of WTe2 shows a nonlinearly dependence on the magnetic field at temperatures below 100 K. At the same time, the Hall resistivity of MoTe2 depends linearly with the magnetic field at temperatures range from 2 to 25 K and a nonlinear contribution appears at 50 K. Along with the known mechanism of compensation/decompensation of electron and hole charge carriers, the nonlinear dependence of the Hall resistivity of WTe2 and MoTe2 single crystals on the magnetic field is associated with the scattering of charge carriers on the surface.

Fizika metallov i metallovedenie. 2024;125(4):453-459
pages 453-459 views

Calorimetric Studies of Phase Transformations in the La1 – xYxMn2Si2 System

Stashkova L., Gerasimov E., Mushnikov N.

Resumo

Differential scanning calorimetry (DSC) is used to determine the magnetic phase transformation temperatures of the La1 – xYxMn2Si2 (x = 0–1) alloys. For the compositions with х from 0 to 0.3, the temperature dependences of DSC signal exhibit λ-like endothermic effects observed near 300 K, which are related to the magnetic phase transition from the ferromagnetic to layered antiferromagnetic structure, and weak anomalies, which are observed in a temperature range of from 458 K for the composition with х = 0 to 323 К for the composition with х = 0.3 upon disordering of the layered antiferromagnetic structure. A clear endothermic peak corresponding to the disordering of interplane antiferromagnetic layered structure was found for the YMn2Si2. The data obtained are used to construct the magnetic phase diagram of the La1–xYxMn2Si2 system in a temperature range of 270–600 К. The differential scanning calorimetry is shown can be successfully used for the determination of temperatures of various magnetic phase transformations in rare-earth intermetallic compounds.

Fizika metallov i metallovedenie. 2024;125(4):460-466
pages 460-466 views

Singular Points of the Radiation Spectrum of Leaky Surface Magnon Polarons

Sukhorukova O., Tarasenko A., Tarasenko S., Shavrov V.

Resumo

Within the dissipation-free approach, for a magnetic layer separating two semi-bounded ideal fluids, it is shown that, at the point of the phonon radiation spectrum where leaky surface magnon polarons of the “dark” state are formed (of interference or symmetry-protected type) at the interface with an acoustically less dense medium, both the numerator and the denominator of the input wave impedance can independently become zero (at the very point of existence of a bound state in the continuum, they vanish simultaneously). The calculation was performed for a two-sublattice model of an antiferromagnet, which simultaneously takes into account magnetoelastic, inhomogeneous exchange, and hyperfine coupling. Conditions have been found under which the mechanisms of formation of bound states in the spectrum of phonon radiation of leaky magnon polarons involving quasi-electronic or quasi-nuclear magnons are fundamentally different: elastodynamic or elastostatic.

Fizika metallov i metallovedenie. 2024;125(4):467-475
pages 467-475 views

Theoretical and Numerical Modeling of Optical Switching of Epitaxial Nanostructures Based on Iron-Garnet Films

Yurlov V., Zvezdin K., Zvezdin A.

Resumo

The paper presents a theoretical analysis of magnetization switching in a gadolinium ferrite garnet film due to the demagnetizing effect of a femtosecond laser pulse. Using the Lagrange formalism for a two-sublattice ferrimagnet, the effective Lagrangian, thermodynamic potential, and Rayleigh dissipative function are obtained. The phase diagram of the ferrite film is analyzed, and the main states of the system are identified. Magnetization switching diagrams and trajectories of the order parameter dynamics of the magnet are constructed. The ranges of magnetic fields, temperatures, and demagnetization values for the most efficient magnetization switching are analyzed.

Fizika metallov i metallovedenie. 2024;125(4):476-484
pages 476-484 views